Achieving C–N bond cleavage in dinuclear metal cyanide complexes
نویسندگان
چکیده
منابع مشابه
METAL-METAL CHARGE TRANSFER IN LnM-CN-FeCl3 COMPLEXES
By combining the organometallic cyanides L n M-CN [L n M = Cp(dppe)Fe, Cp(dppe)Ru, Cp(PPh 3 ) 2 Ru] with FeCl 3 the dinuclear complexes L n M-CN-FeCl 3 were obtained. Structure determinations have revealed configurations close to linear arrays Fe-C-N-Fe and Ru-CN-Fe. From the n(CN) band positions in their IR spectra it can be concluded that FeCl 3 is a very strong electron acceptor. Accordingly...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2011
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c1dt10225g